Palladium/Tris(tert-butyl)phosphine-Catalyzed Suzuki Cross-Couplings in the Presence of Water

Palladium/Tris(tert-butyl)phosphine-Catalyzed Suzuki Cross-Couplings in the Presence of Water
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DOI:
10.1002/adsc.201000267
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发表时间:
2010-08-01
影响因子:
5.4
通讯作者:
Fu, Gregory C.
Fu, Gregory C.
中科院分区:
化学2区
文献类型:
--
作者:
Lou, Sha;Fu, Gregory C.

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二钯三(二亚苄基丙酮)/三(叔丁基)磷四氟硼酸盐/氟化钾二水合物[Pd-2(dba)(3)/[HP(t-Bu)(3)] BF 4/KF中心点H2O]作为一种温和、稳健和用户友好的方法,用于多种芳基和杂芳基卤化物与芳基和杂芳基硼酸的有效Suzuki交叉偶联。
Dipalladiumtris(dibenzylideneacetone)/tris(tert-butyl)phosphomum tetrafluoroborate/potassium fluoride dihydrate [Pd-2(dba)(3)/[HP(t-Bu)(3)]BF4/KF center dot H2O] serves as a mild, robust, and user-friendly method for the efficient Suzuki cross-coupling of a diverse array of aryl and heteroaryl halides with aryl- and heteroarylboronic acids.