Synthesis of peri-Substituted (Naphthalen-1-yl)phosphine Ligands by Rhodium(I)-Catalyzed Phosphine-Directed C-H Arylation

Synthesis of peri-Substituted (Naphthalen-1-yl)phosphine Ligands by Rhodium(I)-Catalyzed Phosphine-Directed C-H Arylation
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通过铑 (I) 催化的膦定向 C-H 芳基化合成邻位取代的 (萘-1-基) 膦配体

DOI:
10.1021/acs.orglett.8b00305
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发表时间:
2018-04-06
期刊:
影响因子:
5.2
通讯作者:
Che, Chi-Ming
Che, Chi-Ming
中科院分区:
化学1区
文献类型:
--
作者:
Luo, Xue;Yuan, Jia;Che, Chi-Ming

文献摘要

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A novel protocol for effective rhodium(I)-catalyzed C-H arylation of tertiary phosphines has been devised. It is amenable to a wide range of substrates and gives the products in moderate to high yields. This strategy provides a simple and efficient route to peri-substituted (naphthalen-1-yl)phosphines.