Reactivities of a barrelene-type dialumane as an equivalent of an Al=Al doubly-bonded species
Reactivities of a barrelene-type dialumane as an equivalent of an Al=Al doubly-bonded species
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DOI：
10.1080/10426507.2015.1128912
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发表时间：
2016-04-02
影响因子：
1.3
通讯作者：
Tokitoh, Norihiro
中科院分区：
文献类型：
--
作者：
Agou, Tomohiro;Nagata, Koichi;Tokitoh, Norihiro
合成了带有大芳基取代基的桶烯型二铝烷，并阐明了它们作为相应二铝烯的合成等价物的反应性。桶烯型二铝烷与[Pt(PCy3)(2)]反应得到相应的亚铝烯(ArAl:)的铂络合物。确定了新获得的含有Al-Al键的环状化合物和铂络合物的结构。
Barrelene-type dialumanes bearing bulky aryl substituents were synthesized, and their reactivity as synthetic equivalents of the corresponding dialumenes was elucidated. Reaction of the barrelene-type dialumanes with [Pt(PCy3)(2)] afforded platinum complexes of the corresponding alumylene (ArAl:). Structures of the newly obtained cyclic compounds containing an Al-Al bond and the platinum complexes were determined.