Uniform wrapping of copper oxide nanocubes by self-controlled copper-catalyzed azide alkyne cycloaddition toward selective carbon dioxide electrocatalysis
Uniform wrapping of copper oxide nanocubes by self-controlled copper-catalyzed azide alkyne cycloaddition toward selective carbon dioxide electrocatalysis
复制标题
自控铜催化叠氮炔环加成均匀包裹氧化铜纳米立方体选择性二氧化碳电催化
DOI：
10.1039/d2cc02017c
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发表时间：
2022
影响因子：
4.9
通讯作者：
Kume Shoko
中科院分区：
文献类型：
--
作者：
Umeda Takuma;Kurome Takeshi;Sakamoto Ayumu;Kubo Kazuyuki;Mizuta Tsutomu;Son Seung Uk;Kume Shoko
氧化铜（I）纳米立方体包裹着一个非常均匀的有机层生长的自控，铜介导的催化。该层有助于在铜纳米立方体用作CO2还原电催化剂期间保持其初始立方结构，由于从表面排除水而通过强烈抑制析氢而导致高CO2还原选择性。
Copper(I) oxide nanocubes were wrapped with an extremely uniform organic layer grown by self-controlled, Cu-mediated catalysis. This layer aided in retaining the initial cubic structure of the copper nanocubes during their use as a CO2 reduction electrocatalyst, resulting in high CO2 reduction selectivity by strong suppression of hydrogen evolution because of exclusion of water from the surface.