Optical Properties of Perylene Microcrystals

Optical Properties of Perylene Microcrystals
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苝微晶的光学性质

DOI:
10.1080/10587259708032275
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发表时间:
1997
影响因子:
0.7
通讯作者:
H. Nakanishi
H. Nakanishi
中科院分区:
化学4区
文献类型:
--
作者:
H. Kasai;Y. Yoshikawa;T. Seko;S. Okada;H. Oikawa;Hiroki Mastuda;A. Watanabe;O. Ito;H. Toyotama;H. Nakanishi

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测量了晶体尺寸从50 nm到1μm范围内茂金属微晶的光学性质。在小于200 nm的微晶体中发现了激子有趣的行为。例如,随着晶体尺寸的减小,微晶中的自陷态激子态向高能方向移动。因此,观察到了自由激子的强烈发光,使自陷态激子的寿命变短。
Abstract The optical properties of perylene microcrystals in wide range of crystal size from 50 ran to 1 μm were measured. The interesting behavior of exciton in microcrystals with less than 200nm was found. For example, with decreasing the crystal size, self-trapped exciton states in microcrystals shifted to the high energy side. Therefore, the strong luminescence from free-exciton was observed, and life time of self-trapped exciton became shorter .