Coordination complexes of gallium(III) and indium(III) halides. V. Trialkyl and mixed alkyl–aryl phosphine complexes of indium(III) chloride, bromide, and iodide
Coordination complexes of gallium(III) and indium(III) halides. V. Trialkyl and mixed alkyl–aryl phosphine complexes of indium(III) chloride, bromide, and iodide
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卤化镓(III) 和卤化铟(III) 的配位络合物。氯化铟(III)、溴化物和碘化物的三烷基和混合烷基-芳基膦络合物。
DOI：
10.1139/v70-325
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发表时间：
1970
影响因子：
1.1
通讯作者：
P. M. Boorman
中科院分区：
文献类型：
--
作者：
A. Carty;T. Hinsperger;P. M. Boorman
合成了新的配合物InX_3L（X = Cl，Br，I; L =三环己基膦），InX_3L_2（X = Cl，Br，I; L =三甲基膦，三乙基膦，二甲基苯基膦），InX_3L_2（X = Cl，Br，L =二苯基乙基膦），InX_3L_3（X = Cl，Br; L =二甲基苯基膦），并通过远红外，拉曼光谱和分子量研究对其结构进行了表征。 反式三角双锥型InX_3L_2和C_3双锥-四面体型InX_3L的结构可以通过它们典型的红外和拉曼光谱容易地表征。本文讨论了三甲基膦、三乙基膦、二甲基苯基膦和二苯基乙基膦加合物的核磁共振化学位移和偶合常数。
The new complexes InX3L (X = Cl, Br, I; L = tricyclohexylphosphine), InX3L2 (X = Cl, Br, I; L = trimethylphosphine, triethylphosphine, dimethylphenylphosphine), InX3L2 (X = Cl, Br, L = diphenylethylphosphine), InX3L3 (X = Cl, Br; L = dimethylphenylphosphine) have been prepared and characterized by far-infrared, Raman, and molecular weight studies. Structures of the types trans trigonal bipyramidal InX3L2 and C3υ ψ-tetrahedral InX3L can be readily characterized by virtue of their typical infrared and Raman spectra. Nuclear magnetic resonance chemical shifts and coupling constants for adducts of trimethylphosphine, triethylphosphine, dimethylphenylphosphine, and diphenylethylphosphine are discussed.