Isoskeletal Schiff base polynuclear coordination clusters: synthetic and theoretical aspects
Isoskeletal Schiff base polynuclear coordination clusters: synthetic and theoretical aspects
复制标题
DOI：
10.1039/c5ce02109j
复制
发表时间：
2016-01
期刊：
影响因子：
3.1
通讯作者：
Kieran Griffiths;V. Dokorou;J. Spencer;A. Abdul-Sada;A. Vargas;G. Kostakis
中科院分区：
文献类型：
--
作者：
Kieran Griffiths;V. Dokorou;J. Spencer;A. Abdul-Sada;A. Vargas;G. Kostakis
这项工作解决并启发了我们系统地构建具有特定缺陷二苯二烷拓扑的通式[TR2Ln2(LX)4(NO3)2(solv)2]的等骨架四核配簇（CCs）的合成方面，利用各种取代的希夫碱有机配体（H2LX）和NiII/CoII和Dy(OTf)3盐。我们的合成工作得到了DFT研究的进一步支持。
This work addresses and enlightens synthetic aspects derived from our effort to systematically construct isoskeletal tetranuclear coordination clusters (CCs) of the general formula [TR2Ln2(LX)4(NO3)2(solv)2] possessing a specific defected dicubane topology, utilizing various substituted Schiff base organic ligands (H2LX) and NiII/CoII and Dy(OTf)3 salts. Our synthetic work is further supported by DFT studies.