Theory of out of equilibrium light-induced phenomena: general discussion
Theory of out of equilibrium light-induced phenomena: general discussion
复制标题
不平衡光致现象理论：一般讨论
DOI：
10.1039/d2fd90036j
复制
发表时间：
2022
影响因子：
3.4
通讯作者：
Alías-Rodríguez M
中科院分区：
文献类型：
--
作者：
Alías-Rodríguez M
James McCusker对Marc Alıas-Rodrıguez的论文展开了讨论：1A 1和5 T2态之间的自旋轨道耦合常数大约比从变温超快时间分辨吸收测量实验确定的大一个数量级。[1]如果你用实验值代替你的计算值，你认为这将如何改变你的机械论图景？
James McCusker opened a discussion of the paper by Marc Alıas-Rodrıguez: The spin–orbit coupling constant between the 1A1 and 5T2 states is roughly an order of magnitude larger than what has been determined experimentally from variable-temperature ultrafast time-resolved absorption measurements. 1 If you were to replace your calculated value with the experimental one, how do you think this would change your mechanistic picture?