Strategy for contra-thermodynamic radical-chain epimerisation of 1,2-diols using polarity-reversal catalysis
Strategy for contra-thermodynamic radical-chain epimerisation of 1,2-diols using polarity-reversal catalysis
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DOI：
10.1016/s0040-4039(00)01502-1
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发表时间：
2000-10-28
影响因子：
1.8
通讯作者：
Roberts, BP
中科院分区：
文献类型：
--
作者：
Dang, HS;Roberts, BP
通过硫醇的极性反转催化已经被应用于提供一种有效的方法，用于通过在自由基链条件下其丙酮化物的差向异构化将适当的1，2-二醇转化为较不稳定或类似稳定的非对映异构体。(C)2000爱思唯尔科技有限公司版权所有。
Polarity-reversal catalysis by thiols has been applied to provide an efficient method for the conversion of appropriate 1,2-diols into less or similarly stable diastereoisomers by epimerisation of their acetonides under radical-chain conditions. (C) 2000 Elsevier Science Ltd. All rights reserved.