Morphology Evolutions and Mechanical Properties of In Situ Fibrillar Polylactic Acid/Thermoplastic Polyurethane Blends Fabricated by Fused Deposition Modeling
Morphology Evolutions and Mechanical Properties of In Situ Fibrillar Polylactic Acid/Thermoplastic Polyurethane Blends Fabricated by Fused Deposition Modeling
复制标题
熔融沉积成型原位纤维状聚乳酸/热塑性聚氨酯共混物的形态演变和机械性能
DOI：
10.1002/mame.201900107
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发表时间：
2019-07
影响因子：
3.9
通讯作者：
Xu Gaojie
中科院分区：
文献类型：
--
作者：
Wang Jianye;Zhang Yifan;Sun Wei;Chu Shaosheng;Chen Tao;Sun Aihua;Guo Jianjun;Xu Gaojie
There are many studies devoted to conquer the strength–ductility trade‐off dilemma of polylactic acid (PLA) by flexible elastomer blending, like thermoplastic polyurethane (TPU), but little is known about the effects of the fused deposition modeling (FDM) process on the in situ morphology evolution of the elastomers. In this work, the effects of the three successive drawing processes in FDM on the morphology evolution of the dispersed TPU in the PLA matrix, and the toughening behavior of FDM‐printed PLA/microfibrillar‐TPU blends, are systematically studied. The results manifest that the average length of the TPU microfibrils can be turned precisely from 67.24 to 103.72 µm. The in situ microfibrillation process can remarkably improve the PLA crystallization capability and interfacial interaction. More interestingly, the inevitable decrease of impact strength of FDM‐printed part induced by the voids is compensated by the network‐like TPU microfibrils formed during the layer‐by‐layer printing. These inspiring findings suggest that the in situ fibrillation process can conquer the inherent weaknesses of both FDM process and PLA materials, providing facile and efficient method for fabricating high toughness PLA parts.
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影响因子：
15.1
作者：
Kakroodi, Adel Ramezani;Kazemi, Yasamin;Park, Chul B.
通讯作者：
Park, Chul B.
影响因子：
9.5
作者：
Ojijo, Vincent;Ray, Suprakas Sinha;Sadiku, Rotimi
通讯作者：
Sadiku, Rotimi
影响因子：
29.4
作者：
S. Fakirov;M. Evstatiev
通讯作者：
S. Fakirov;M. Evstatiev
采用原位纳米纤化和纳米多孔注射成型获得轻质、坚韧的纳米多孔 PP/PTFE 纳米复合泡沫，表面无缺陷
影响因子：
15.1
作者：
Wang, Guilong;Zhao, Guoqun;Park, Chul B.
通讯作者：
Park, Chul B.
影响因子：
64.8
作者：
Gantenbein, Silvan;Masania, Kunal;Studart, Andre R.
通讯作者：
Studart, Andre R.