Diastereomeric control of photoinduced Diels-Alder reactions of 1-anthracen-9-yl-ethanol by hydrogen-bonding effects
Diastereomeric control of photoinduced Diels-Alder reactions of 1-anthracen-9-yl-ethanol by hydrogen-bonding effects
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DOI：
10.1016/s0040-4039(01)01742-7
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发表时间：
2001-11-12
影响因子：
1.8
通讯作者：
Jones, S
中科院分区：
文献类型：
--
作者：
Atherton, JCC;Jones, S
1-蒽-9-基乙醇与马来酸酐的光诱导Diels-Alder反应具有高的非对映选择性，但与类似的O化合物相比，其选择性完全相反。氢键效应已被确定为决定这种选择性的主要因素。(C)2001爱思唯尔科技有限公司版权所有。
Photoinduced Diels-Alder reactions of 1-anthracen-9-yl-ethanol with maleic anhydride proceed with high diastereoselection but with complete reversal of the sense of selectivity compared to analogous O compound, Hydrogen-bonding effects have been established as the predominant factors in determining this selectivity. (C) 2001 Elsevier Science Ltd. All rights reserved.