Synthesis of a-Substituted Diphenylphosphinocarboxylic Acids and Their Palladium Complexes

Synthesis of a-Substituted Diphenylphosphinocarboxylic Acids and Their Palladium Complexes
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α-取代二苯基膦甲酸及其钯配合物的合成

DOI:
10.1055/s-0036-1588328
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发表时间:
2016
期刊:
影响因子:
2
通讯作者:
Fernández-Ibáñez M
Fernández-Ibáñez M
中科院分区:
化学4区
文献类型:
--
作者:
Fernández-Ibáñez M

文献摘要

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本文描述了用简单酯和二苯基氯膦-硼烷作为现成的原料合成α-取代膦乙酸的一般和有效的方法。本文还报道了由2-乙基二苯基膦乙酸衍生的相应钯配合物的形成和结构。
A general and efficient synthesis of α-substituted phosphinoacetic acids using simple esters and diphenylchlorophosphine–borane as readily available starting materials is here described. The formation and structure of the corresponding palladium complex derived from 2-ethyl diphenylphosphinoacetic acid is also reported.