Confocal Laser Scanning Microscope Analysis of Antimony Porphyrin Chromophore Immobilized on Silica-gel Beads
Confocal Laser Scanning Microscope Analysis of Antimony Porphyrin Chromophore Immobilized on Silica-gel Beads
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DOI：
10.1246/cl.2005.1484
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发表时间：
2005-09
影响因子：
1.6
通讯作者：
Jin Matsumoto;Tomokazu Fuchikawa;Yasuhiro Komiya;Y. Fueda;Tomoko Matsumoto;T. Shiragami;M. Yasuda
中科院分区：
文献类型：
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作者：
Jin Matsumoto;Tomokazu Fuchikawa;Yasuhiro Komiya;Y. Fueda;Tomoko Matsumoto;T. Shiragami;M. Yasuda
用二羟基xoantimony [4-（n -丁二酰氧羰基）苯基]triphenylporphyrin与nh2 - sio2反应，将二羟基xoantimony(V) tetraphenylporphyrin发色团（SbTPP）固定在3-氨丙基硅胶（nh2 - sio2）上。共聚焦激光扫描显微镜对配合物的光谱分析表明，SbTPP与sio2上残留的氨基相互作用。配合物与Et 2nh的光反应诱导了脱金属。
Dihydroxoantimony(V) tetraphenylporphyrin chromophore (SbTPP) was immobilized on 3-aminopropyl-silica gel (NH 2 -SiO 2 ) by the reaction of dihydroxoantimony [4-(N-succinimidyloxycarbonyl)phenyl]triphenylporphyrin with NH 2 -SiO 2 . Spectroscopic analysis of the complex by confocal laser scanning microscope suggested the interaction of SbTPP with the residual amino group on SiO 2 . The photoreaction of the complex with Et 2 NH induced the demetallation.