Understanding gold nanoparticle dissolution in cyanide-containing solution via impact-chemistry.
Understanding gold nanoparticle dissolution in cyanide-containing solution via impact-chemistry.
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DOI：
10.1039/c8cp05154b
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发表时间：
2018-11
期刊：
影响因子：
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通讯作者：
A. Suherman;G. Zampardi;S. Kuss;E. E. Tanner-E.;Hatem M. A. Amin;N. Young;R. Compton
中科院分区：
文献类型：
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作者：
A. Suherman;G. Zampardi;S. Kuss;E. E. Tanner-E.;Hatem M. A. Amin;N. Young;R. Compton
研究了柠檬酸盐修饰的金纳米颗粒（AuNPs）在含氰化物（CN-）溶液中的电化学溶解。结果发现，金纳米粒子表现出不同的溶解行为相比，单一的颗粒作为合奏。在单颗粒水平上，在浓度大于或等于35.0 mM CN-和1.0 V的电位下实现了60 nm AuNP的几乎完全氧化。
The electrochemical dissolution of citrate-capped gold nanoparticles (AuNPs) was studied in cyanide (CN-) containing solutions. It was found that the gold nanoparticles exhibited different dissolution behaviours as ensembles compared to the single particles. At the single particle level, a nearly complete oxidation of 60 nm AuNPs was achieved at concentrations greater than or equal to 35.0 mM CN- and at a potential of 1.0 V. Mechanistic insights and rate data are reported.