187. Phthalocyanines. Part IX. Derivatives of thiophen, thionaphthen, pyridine, and pyrazine, and a note on the nomenclature
187. Phthalocyanines. Part IX. Derivatives of thiophen, thionaphthen, pyridine, and pyrazine, and a note on the nomenclature
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187. 酞菁。
DOI：
10.1039/jr9370000911
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发表时间：
1937
期刊：
影响因子：
--
通讯作者：
J. Wright
中科院分区：
文献类型：
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作者：
R. Linstead;E. G. Noble;J. Wright
RP LINSTEAD，EG NOBLE和JM WRIGHT。本文及随后的三篇论文主要从两个方面对酞菁的化学进行了研究：（1）研究了从杂环化合物而不是芳香族化合物中间体得到类似化合物的可能性（第九和第十部分）;（2）努力弥补酞菁和卟啉之间的差距。这两个群体之间的相似性已经讨论过了（J，1934，1033; Ann. Reports，1935，32，359）。基本结构之间的差异是两个：酞菁（P）含有四个额外的稠合苯环和四个连接氮原子，代替了卟啉（Q，X= CH）的四个亚甲基。为了将这两个系列更紧密地联系起来，我们研究了制备（a）具有氮键但不具有稠合苯环的类似酞菁的化合物（第X部分）和（B）苯并卟啉，即，具有亚甲基连接和稠合苯环的类似化合物（第十一部分）。这一领域的扩展产生了对更精确命名的需要。酞菁的名称现在已被很好地确立用于由式（P）表示的一般类型的化合物。建议将术语卟啉用于酞菁分子的中心环系统，即用于由式（Q，X= N）表示的结构。通过附加适当的前缀来命名单个化合物。因此，酞菁本身在此基础上的系统名称是四苯并吡嗪，相应的四个吡啶环取代四个苯的化合物成为四吡啶吡嗪。为了避免不必要的复杂性，不建议使用系统名称。
By RP LINSTEAD, EG NOBLE, and JM WRIGHT. THIS and the three following papers are concerned with investigations of the chemistry of phthalocyanines in two main directions:(1) the possibility of obtaining similar compounds from heterocyclic instead of aromatic intermediates has been examined (Parts IX and X);(2) efforts have been made to bridge the gap between phthalocyanines and porphyrins. The resemblance between these two groups has already been discussed (J., 1934, 1033; Ann. Reports, 1935, 32, 359). The differences between the basic structures are two: phthalocyanine (P) contains four additional fused benzene rings and four linking nitrogen atoms in place of the four methene groups of porphin (Q, X= CH). To connect the two series more closely we have examined the possibility of preparing (a) compounds resembling phthalocyanine with nitrogen links but possessing no fused benzene rings (Part X), and (b) benzporphyrins, Le., analogous compounds with methene links and fused benzene rings (Part XI).This extension of the field has created the need for a more precise nomenclature. The name phthalocyanine is now well established for compounds of the general type indicated by formula (P). It is proposed to use the term porphyraxine for the central ring system of the phthalocyanine molecule, that is, for the structure represented by formula (Q, X= N). Individual compounds are named by attaching an appropriate prefix. Thus the systematic name for phthalocyanine itself on this basis is tetrabenzporphyrazine and the corresponding compound with four pyridine rings in place of four benzenes becomes tetrapyridinoporphyrazine. To avoid undue complication it is not proposed to use the systematic names