Derivatization of Fullerenes: An Organic Chemistry Laboratory
Derivatization of Fullerenes: An Organic Chemistry Laboratory
复制标题
富勒烯的衍生化：有机化学实验室
DOI：
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发表时间：
2006
期刊：
影响因子：
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通讯作者：
M. Cooper
中科院分区：
文献类型：
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作者：
Charles T. Cox;M. Cooper
富勒烯化学是一个迅速发展的研究领域，在过去的十年里有了巨大的增长。然而，很少有富勒烯化学被纳入本科生的讲座或实验室，而且在这本杂志中只有两篇关于这一化学的贡献。考虑到这一点，开发了两个本科有机化学实验室，详细介绍了富勒烯衍生物的合成，使用Bingel(卡宾插入)和Prato(1，3-偶极加成)方案。这些实验适用于第二学期的有机化学实验室。这些实验不仅介绍了富勒烯化学，而且强调和加强了关键技术，包括回流、IR、1H核磁共振、UV-Vis、TLC和柱层析。
Fullerene chemistry is a rapidly expanding research field that has grown immensely over the past decade. However, little fullerene chemistry is being incorporated into undergraduate lectures or laboratories, and there have only been two contributions in this Journal concerning this chemistry. With this in mind, two undergraduate organic chemistry laboratories were developed detailing the synthesis of fullerene derivatives, using the Bingel (carbene insertion) and Prato (1,3-dipolar addition) protocols. These experiments are appropriate for a second-semester organic chemistry laboratory. The experiments not only introduce fullerene chemistry, but they emphasize and reinforce key techniques including refluxing, IR, 1H NMR, UV–vis, TLC, and column chromatography.