Free radicals in lipid bilayers: new probes of lipid radical dynamics

Free radicals in lipid bilayers: new probes of lipid radical dynamics
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DOI:
10.1021/ja00315a070
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发表时间:
1984-02
影响因子:
15
通讯作者:
N. Porter;R. Petter;W. Brittain
N. Porter;R. Petter;W. Brittain
中科院分区:
化学1区
文献类型:
--
作者:
N. Porter;R. Petter;W. Brittain

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可能以缓慢的构象变化的形式发生,这些对效应的影响是感兴趣的。然而,大多数过程将是快速的,相比之下,和实验可以被认为是一种方法,以恢复极端缩小条件下的高分子量化合物。我们认为这类实验的一个合适的缩写是CAMELSPIN(适用于锁定自旋模拟的最小分子的交叉再松弛)。滑冰爱好者对这个词的起源不会有什么困难。本研究由美国国立卫生研究院资助AM16532,并使用美国国立卫生研究院资助RR00292,位于宾夕法尼亚州匹兹堡的生物医学研究核磁共振设施的600-MHz核磁共振光谱仪进行。
might occur in the form of slow conformational changes, and the influence of these on the effects is of interest. However, most processes will be fast compared to,, and the experiment may be thought of as a way to restore the extreme narrowing condition for higher molecular weightcompounds. We think a suitable acronym for this type of experiment is CAMELSPIN (cross-re-laxation appropriate for minimolecules emulated by locked spins). Ice-skating enthusiasts will have no difficulty with the originof the term.Acknowledgment. This research is supported by NIH grant AM16532 and was performed by using the 600-MHz NMR spectrometer of the NMR Facility for BiomedicalStudies, Pittsburgh, PA, supported by NIH Grant RR00292.