PREPARATION, SPECTROSCOPIC CHARACTERIZATION, AND MOLECULAR STRUCTURE OF COPPER(I) ALIPHATIC THIOLATE COMPLEXES
PREPARATION, SPECTROSCOPIC CHARACTERIZATION, AND MOLECULAR STRUCTURE OF COPPER(I) ALIPHATIC THIOLATE COMPLEXES
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脂肪族硫醇铜(I)络合物的制备、光谱表征和分子结构
DOI：
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发表时间：
1998
期刊：
影响因子：
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通讯作者：
Y. Moro
中科院分区：
文献类型：
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作者：
K. Fujisawa;Sadako Imai;N. Kitajima;Y. Moro
合成了一个二配位的脂肪族单硫醇铜（I）配合物[NEt 4][Cu（SAd）2]（1）和一个脂肪族单硫醇铜（I）簇合物[NEt 4][Cu 5（SAd）6]（2），并通过X射线晶体学、荧光光谱、远红外光谱和拉曼光谱以及紫外光谱对它们进行了表征。这些物理化学性质的二方网站进行了比较的三方之一。紫外区的MLCT能量和Cu-S伸缩频率可以用来区分铜中心的配位数和几何形状。
A two-coordinate aliphatic monothiolate copper(I) complex ([NEt4][Cu(SAd)2] (1)) and an aliphatic monothiolate copper(I) cluster ([NEt4][Cu5(SAd)6] (2)) were synthesized and characterized in the solid state by X-ray crystallography and by luminescence, FT-far-IR, and FT-Raman spectroscopy and in solution by UV spectroscopy. These physicochemical properties of the digonal site were compared with those of the trigonal one. MLCT energies in the UV region and Cu−S stretching frequencies may be used to differentiate the coordination numbers and geometries of the copper centers.