A first transition series pseudotetrahedral oxynitride anion:: Synthesis and characterization of Ba2VO3N
A first transition series pseudotetrahedral oxynitride anion:: Synthesis and characterization of Ba2VO3N
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DOI：
10.1021/ja0122896
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发表时间：
2002-04-03
影响因子：
15
通讯作者：
Rosseinsky, MJ
中科院分区：
文献类型：
--
作者：
Clarke, SJ;Chalker, PR;Rosseinsky, MJ
反应性氧化物前体的氨解提供了钒（V）相Ba 2 VO 3 N，其通过X射线和中子粉末衍射以及拉曼光谱显示含有假四面体VO 3 N4-阴离子。这是第一过渡系列金属的这种物质的第一个例子。
Ammonolysis of reactive oxide precursors affords the vanadium(V) phase Ba2VO3N that is shown by X-ray and neutron powder diffraction and Raman spectroscopy to contain pseudotetrahedral VO3N4- anions. This is the first example of such species for the first transition series metals.