3-Chloro-3,3-bis(triphenylphosphine-P)-1,2-dicarba-3-rhoda-closo-dodecaborane– Dichloromethane (1/1.1)
3-Chloro-3,3-bis(triphenylphosphine-P)-1,2-dicarba-3-rhoda-closo-dodecaborane– Dichloromethane (1/1.1)
复制标题
3-氯-3,3-双(三苯基膦-P)-1,2-二卡巴-3-罗达-氯代-十二硼烷–二氯甲烷 (1/1.1)
DOI:
--
复制
发表时间:
1996
期刊:
影响因子:
--
通讯作者:
T. Spalding
中科院分区:
文献类型:
--
作者:
G. Ferguson;P. Mceneaney;T. Spalding
The title compound, [3,3-(PPh 3 ) 2 -3-Cl-3,1,2-RhC 2 B 9 H 11 ] or [RhCl(C 2 H 11 B 9 )(C 18 H 15 P) 2 ].1.1CH 2 Cl 2 , contains a triangulated icosahedral closo-RhC 2 B 9 cage. Principal bond distances are Rh-Cl 2.423 (2), Rh-P 2.373 (2) and 2.383(2), Rh-C 2.190(6) and 2.191(6), and Rh-B 2.203 (8)-2.289 (8) A. The conformation of the Rh(PPh 3 ) 2 Cl group above the C 2 B 3 face of the dicarbaborane ligand is such that the Rh-Cl bond is located above the cage C-C vector.