RAPID AND MILD DEOXYGENATION OF ORGANOHETEROATOM OXIDES WITH THE EFFICIENT ELECTRON-TRANSFER SYSTEM SMI2 TETRAHYDROFURAN HEXAMETHYLPHOSPHORIC TRIAMIDE
RAPID AND MILD DEOXYGENATION OF ORGANOHETEROATOM OXIDES WITH THE EFFICIENT ELECTRON-TRANSFER SYSTEM SMI2 TETRAHYDROFURAN HEXAMETHYLPHOSPHORIC TRIAMIDE
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DOI：
10.1039/c39890000298
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发表时间：
1989-03-01
影响因子：
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通讯作者：
YAMAGUCHI, M
中科院分区：
文献类型：
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作者：
HANDA, Y;INANAGA, J;YAMAGUCHI, M
用化学计量量的SmI2在四氢呋喃-六甲基磷酸三酰胺中快速脱氧了多种有机杂原子氧化物，如硫化物、硫酮、n -氧化物、氧化膦和氧化锡。
A variety of organoheteroatom oxides such as sulphoxides, sulphones, N-oxides, a phosphine oxide, and an organo tin oxide were rapidly deoxygenated at room temperature by using a stoicheiometric amount of SmI2 in tetrahydrofuran–hexamethylphosphoric triamide.