A Porous Coordination Network Catalyzes an Olefin Isomerization Reaction in the Pore
A Porous Coordination Network Catalyzes an Olefin Isomerization Reaction in the Pore
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DOI：
10.1021/ja908794n
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发表时间：
2010-01-13
影响因子：
15
通讯作者：
Fujita, Makoto
中科院分区：
文献类型：
--
作者：
Ohara, Kazuaki;Kawano, Masaki;Fujita, Makoto
全反式视网膜有效地扩散到由锌离子和缺电子的三氮杂环配体组成的多孔配位网络的孔洞中。被包裹的视网膜在溶液中被异构化成13-顺式，并很容易被全反式视网膜取代，从而揭示了多孔网络对视网膜异构化的催化作用。
All-trans retinal efficiently diffused into the pore of a porous coordination network consisting of Znl(2) and an electron-deficient triazine-cored ligand. Enclathrated retinal was isomerized into the 13-cis form and easily replaced with all-trans retinal in solution, thus revealing the catalysis of retinal isomerization by the porous network.