Distinct activation of Cu-MOR for direct oxidation of methane to methanol

Distinct activation of Cu-MOR for direct oxidation of methane to methanol
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DOI:
10.1039/c7cc00467b
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发表时间:
2017-04-14
影响因子:
4.9
通讯作者:
Yi, Jongheop
Yi, Jongheop
中科院分区:
化学2区
文献类型:
--
作者:
Kim, Younhwa;Kim, Tae Yong;Yi, Jongheop

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Cu-MOR 的 N2O 活化在高温下增强了甲醇产量,其程度比最佳条件下 O-2 的活化更大。 N2O 活化导致甲醇产量的增加归因于活性铜中心的容易形成,而没有形成非活性中间体物质。
N2O activation of Cu-MOR enhanced methanol production at elevated temperatures, to a greater extent than activation by O-2 under optimal conditions. The increase in methanol production by N2O activation was attributed to the facile formation of an active copper center with no formation of inactive intermediate species.