Luminescent Complexes Beyond the Platinum Group: The d10 Avenue
Luminescent Complexes Beyond the Platinum Group: The d10 Avenue
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DOI：
10.1002/chin.200834231
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发表时间：
2008-08
期刊：
影响因子：
--
通讯作者：
A. Barbieri;G. Accorsi;N. Armaroli
中科院分区：
文献类型：
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作者：
A. Barbieri;G. Accorsi;N. Armaroli
发光金属配合物是照明、分析探针和激光等应用的关键材料。在许多情况下，使用基于贵金属（即铂族）和稀土金属的化合物，其通常相当昂贵且存在环境问题。近年来，人们对基于不太传统但更丰富和更便宜的金属元素的发光配合物的兴趣越来越大。在这种情况下，具有d10电子构型的金属化合物发挥着突出的作用，这也归功于它们的发光水平的多功能性，其可以是配体中心的、电荷转移的，或者在多核化合物的情况下，甚至是金属中心的性质。在这里，我们集中在一些选定的例子Cu（I），Ag（I），Au（I），Zn（II）和Cd（II）的发光配合物，提出一些可能的路线，有前途的和前所未有的发射材料。
Luminescent metal complexes are key materials for several applications such as lighting, analytical probes, and lasers. In many cases compounds based on precious (i.e. platinum group) and rare earth metals are utilized, which are often rather expensive and environmentally problematic. In recent years, interest is growing in luminescent complexes based on less traditional but more abundant and cheaper metal elements. In this scenario compounds of metals with a d10 electronic configuration are playing a prominent role, also thanks to the versatility of their luminescent levels which can be of ligand centred, charge transfer or, in the case of polynuclear compounds, even metal-centred nature. Here we focus on some selected examples of Cu(I), Ag(I), Au(I), Zn(II) and Cd(II) luminescent complexes to suggest some possible routes towards promising and unprecedented emitting materials.