Block Copolymers in Solution: Fundamentals and Applications
Block Copolymers in Solution: Fundamentals and Applications
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发表时间：
2005-09
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通讯作者：
I. Hamley
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作者：
I. Hamley
序言。1.导论.参考资料。2.稀溶液中的中性嵌段共聚物。2.1导论. 2.2研究胶束化的技术。2.3 PEO基嵌段共聚物中的胶束化。2.4苯乙烯嵌段共聚物的胶束化。2.5 cmc的测定。2.6胶束化热力学2.7胶束化和胶束尺寸：理论和模拟。2.8胶束尺寸：实验与理论的比较。2.9胶束之间的相互作用。2.10胶束化动力学。2.11动态模式。2.12特定类型的胶束。2.13混合溶剂中的胶束化。2.14混合胶束。2.15嵌段共聚物/表面活性剂复合物。2.16复杂的形态。2.17囊泡。2.18胶束中的结晶。参考资料。3.浓缩溶液。3.1了解相图。3.2含PEO嵌段共聚物的相行为3.3甘精胰岛素3.4有序-无序相变。3.5有序相变。3.6域间距缩放和溶剂分布曲线。3.7半稀嵌段共聚物溶液理论。3.8对相图的理论理解。3.9流动对齐。3.10动力学参考资料。4.聚电解质嵌段共聚物。4.1胶束化。4.2链构象。4.3理论4.4 Polyion Complexes. 4.5共聚物-表面活性剂复合物。4.6与其他分子的复合。4.7甘精胰岛素4.8肽嵌段共聚物电解质溶液中的层次有序。参考资料。5.吸附。5.1导论. 5.2在空气-水界面的吸附。5.3在固体基质上的吸附。5.4表面力实验5.5模拟吸附。参考资料。6.应用6.1表面活性剂/去污剂。6.2增溶、乳化和稳定。6.3药物递送。6.4生物可降解嵌段共聚物胶束。6.5温敏胶束系统。6.6含金属共聚物胶束和纳米反应器。6.7囊泡。6.8分离介质。6.9模板化。6.10膜。6.11其他应用程序。参考资料。指数.
Preface. 1. Introduction. References. 2. Neutral Block Copolymers in Dilute Solution. 2.1 Introduction. 2.2 Techniques for Studying Micellization. 2.3 Micellization in PEO-based Block Copolymers. 2.4 Micellization in Styrenic Block Copolymers. 2.5 Determination of cmc. 2.6 Thermodynamics of Micellization. 2.7 Micellization and Micelle Dimensions: Theory and Simulation. 2.8 Micelle Dimensions: Comparison Between Experiment and Theory. 2.9 Interaction between Micelles. 2.10 Dynamics of Micellization. 2.11 Dynamic Modes. 2.12 Specific Types of Micelles. 2.13 Micellization in Mixed solvents. 2.14 Mixed micelles. 2.15 Block Copolymer/Surfactant complexes. 2.16 Complex Morphologies. 2.17 Vesicles. 2.18 Crystallization in Micelles. References. 3. Concentrated Solutions. 3.1 Understanding Phase Diagrams. 3.2 Phase Behaviour of PEO-containing Block Copolymers. 3.3 Gelation. 3.4 Order-Disorder Phase Transition. 3.5 Order-order Phase Transitions. 3.6 Domain Spacing Scaling, and Solvent Distribution profiles. 3.7 Semidilute Block Copolymer Solution Theory. 3.8 Theoretical understanding of Phase Diagrams. 3.9 Flow Alignment. 3.10 Dynamics. References. 4. Polyelectrolyte Block Copolymers. 4.1 Micellization. 4.2 Chain Conformation. 4.3 Theory. 4.4 Polyion Complexes. 4.5 Copolymer-surfactant complexes. 4.6 Complexation with other Molecules. 4.7 Gelation. 4.8 Hierarchical Order in Peptide Block Copolyelectrolyte Solutions. References. 5. Adsorption. 5.1 Introduction. 5.2 Adsorption at the Air-Water Interface. 5.3 Adsorption on Solid Substrates. 5.4 Surface Forces Experiments. 5.5 Modelling Adsorption. References. 6. Applications 6.1 Surfactancy/Detergency. 6.2 Solubilisation, Emusification and Stabilization. 6.3 Drug Delivery. 6.4 Biodegradable Block Copolymer Micelles. 6.5 Thermoresponsive Micellar Systems. 6.6 Metal-Containing Copolymer Micelles and Nanoreactors. 6.7 Vesicles. 6.8 Separation Media. 6.9 Templating. 6.10 Membranes. 6.11 Other Applications. References. Index.