Efficient and green telescoped process to 2-methoxy-3-methyl-[1,4]benzoquinone
Efficient and green telescoped process to 2-methoxy-3-methyl-[1,4]benzoquinone
复制标题
DOI：
10.1021/jo0522512
复制
发表时间：
2006-02-17
影响因子：
3.6
通讯作者：
Bjorsvik, HR
中科院分区：
文献类型：
--
作者：
González, RR;Gambarotti, C;Bjorsvik, HR
本发明公开了一种制备2-甲氧基-3-甲基-[1，4]苯醌的缩短方法。当这种新的方法相比，目前流行的方法，利用Na 2Cr 2 O 7作为氧化剂，新的方法代表了一个高产率（95%），绿色，和环境友好的替代与H2 O2和HNO 3作为氧化剂和CH 3COOH作为反应介质。
A telescoped process for the preparation of 2-methoxy-3methyl-[1,4]benzoquinone is disclosed. When this novel process is compared to the prevailing method that utilizes Na2Cr2O7 as the oxidant, the novel process represents a high yielding (95%), green, and environmentally benign alternative with H2O2 and HNO3 as the oxidants and CH3COOH as the reaction medium.