Activation of hydrocarbon C-H bonds by iodosylbenzene: how does it compare with iron(IV)-oxo oxidants?
Activation of hydrocarbon C-H bonds by iodosylbenzene: how does it compare with iron(IV)-oxo oxidants?
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DOI：
10.1039/b820812c
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发表时间：
2009-01-01
影响因子：
4.9
通讯作者：
de Visser, Sam P.
中科院分区：
文献类型：
--
作者：
Kim, Soo Jeong;Latifi, Reza;de Visser, Sam P.
对碘基苯（iodosylbenzene, PhIO）反应性的实验和理论研究表明，PhIO能够通过吸氢机制激活碳氢化合物的弱C-H键。
Combined experimental and theoretical studies on the reactivity of iodosylbenzene (PhIO) show that PhIO is capable of activating weak C-H bonds of hydrocarbons via a hydrogen abstraction mechanism.