DIRECT REGIOSPECIFIC ALLYLIC AMINATION VIA SILICON INDUCED PERICYCLIC-REACTIONS - A NOVEL SYNTHESIS OF GAMMA-VINYL GABA
DIRECT REGIOSPECIFIC ALLYLIC AMINATION VIA SILICON INDUCED PERICYCLIC-REACTIONS - A NOVEL SYNTHESIS OF GAMMA-VINYL GABA
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DOI：
10.1016/s0040-4020(01)86670-9
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发表时间：
1988-01-01
期刊：
影响因子：
2.1
通讯作者：
GADRAS, A
中科院分区：
文献类型：
--
作者：
DELERIS, G;DUNOGUES, J;GADRAS, A
N-亚硫基苯磺酰胺与烯烃的烯反应产物硅烷化反应引起[2，3]Sigmatroous重排，得到烯丙胺衍生物。该反应用于合成γ-乙烯基氨基丁酸。
Silylation of the product of the ene reaction of N-sulphinylbenzene sulphonamide and an alkene induces a [2,3]sigmatropic rearrangement, leading to an allylamine derivative. The reaction is used in a synthesis of .gamma.-vinyl GABA.