BRIDGED POLYCYCLIC COMPOUNDS .6. THE PHOTOISOMERIZATION OF BICYCLO[2,2,1]HEPTA-2,5-DIENE-2,3-DICARBOXYLIC ACID TO QUADRICYCLO[2,2,1,02,6,03,5]HEPTANE-2,3-DICARBOXYLIC ACID
BRIDGED POLYCYCLIC COMPOUNDS .6. THE PHOTOISOMERIZATION OF BICYCLO[2,2,1]HEPTA-2,5-DIENE-2,3-DICARBOXYLIC ACID TO QUADRICYCLO[2,2,1,02,6,03,5]HEPTANE-2,3-DICARBOXYLIC ACID
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DOI：
10.1021/ja01541a043
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发表时间：
1958-01-01
影响因子：
15
通讯作者：
SNELL, RL
中科院分区：
文献类型：
--
作者：
CRISTOL, SJ;SNELL, RL
本发明描述了通过辐射双环[2，2，1]庚-2，5-二烯-2，3-二羧酸（IV）来合成四环[2，2，1，02，6，03，5]庚-2，3-二羧酸（III）。这是首次报道的含该环体系的化合物。本文叙述了Ⅲ的某些反应和性质，并由此确定了辐照产物的结构。
The synthesis of quadricyclo [2, 2, l, 02, 6, 03, 5] heptane-2, 3-dicarboxylic acid (III) by irradiation of bicyclo [2, 2, 1 Jhepta-2.5-diene-2, 3-dicarboxylic acid (IV) is described. This represents the first compound reported with thisring system. Cer-tain reactions and properties of III are described, which lead to the assignment of structure to the irradiation product.