Ring-opening of epoxyalcohols by diethylaluminium cyanide. Regio- and stereoselective synthesis of 1-cyano-2,3-diols
Ring-opening of epoxyalcohols by diethylaluminium cyanide. Regio- and stereoselective synthesis of 1-cyano-2,3-diols
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DOI：
10.1016/s0040-4039(98)02520-9
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发表时间：
1999-01-29
影响因子：
1.8
通讯作者：
Norbedo, S
中科院分区：
文献类型：
--
作者：
Benedetti, F;Berti, F;Norbedo, S
二乙基氰化铝是2，3-环氧醇在温和条件下开环的高选择性试剂，反应发生在C-3，构型颠倒，生成1-氰基-2，3-二醇。(C)1999爱思唯尔科学有限公司。保留所有权利。
Diethylaluminium cyanide is a highly selective reagent for the ring opening of 2,3-epoxyalcohols under mild conditions; the reaction takes place at C-3, with inversion of configuration, to give 1-cyano-2,3-diols. (C) 1999 Elsevier Science Ltd. All rights reserved.