Highly selective chromium-based ethylene trimerisation catalysts with bulky diphosphinoamine ligands

Highly selective chromium-based ethylene trimerisation catalysts with bulky diphosphinoamine ligands
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DOI:
10.1039/b412431f
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发表时间:
2005-01-01
影响因子:
4.9
通讯作者:
Overett, MJ
Overett, MJ
中科院分区:
化学2区
文献类型:
--
作者:
Blann, K;Bollmann, A;Overett, MJ

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原位制备的含大体积二膦胺(PNP)配体的铬催化剂,经MAO活化后,是乙烯三聚制1-己烯的极其有效的催化剂。
In situ prepared chromium catalysts containing bulky diphosphinoamine (PNP) ligands, upon activation with MAO, are extremely efficient catalysts for the trimerisation of ethylene to 1-hexene.