Temperature dependence of conductivity enhancement induced by nanoceramic fillers in polymer electrolytes
Temperature dependence of conductivity enhancement induced by nanoceramic fillers in polymer electrolytes
复制标题
聚合物电解质中纳米陶瓷填料引起的电导率增强的温度依赖性
DOI:
10.1063/1.4803185
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发表时间:
2013-04
影响因子:
4
通讯作者:
王波
中科院分区:
文献类型:
--
作者:
王波
The microstructure and ionic conductivity of polymer nanocomposite electrolytes doped with ZnO have been systematically studied. Compared with the undoped one, a less crystalline phase, a restrained main chain movement, a reduced symmetry in the configuration of ethylene oxide/lithium ion, and an at least five-fold increase in conductivity were observed for the filler incorporated electrolyte. Lewis acid-base interactions are determining in causing these changes. The temperature dependence of conductivity is explained by the Vogel-Tammann-Fulcher equation based on the free volume theory. The mechanism of temperature dependent conductivity enhancement is interpreted by a modeling function proposed.
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影响因子:
10.9
作者:
王波
通讯作者:
王波
影响因子:
5.5
作者:
Yuchan Zhu;Bo Wang;W. Gong;Ling-Ge Kong;Q. Jia
通讯作者:
Yuchan Zhu;Bo Wang;W. Gong;Ling-Ge Kong;Q. Jia
影响因子:
6.3
作者:
P. Kirkegaard;M. Eldrup;O. Mogensen;N. Pedersen
通讯作者:
P. Kirkegaard;M. Eldrup;O. Mogensen;N. Pedersen
DOI:
10.1021/jp3036499
发表时间:
2012-06
期刊:
The journal of physical chemistry. B
影响因子:
--
作者:
B. K. Money;K. Hariharan;J. Swenson
通讯作者:
B. K. Money;K. Hariharan;J. Swenson
影响因子:
6.6
作者:
Jayathilaka, PARD;Dissanayake, MAKL;Mellander, BE
通讯作者:
Mellander, BE