Highly enantioselective spiro cyclization of 1,6-enynes catalyzed by cationic skewphos rhodium(I) complex.
Highly enantioselective spiro cyclization of 1,6-enynes catalyzed by cationic skewphos rhodium(I) complex.
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DOI：
10.1039/b310789b
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发表时间：
2004-05
影响因子：
4.9
通讯作者：
K. Mikami;Yukinori Yusa;M. Hatano;Kazuki Wakabayashi;K. Aikawa
中科院分区：
文献类型：
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作者：
K. Mikami;Yukinori Yusa;M. Hatano;Kazuki Wakabayashi;K. Aikawa
具有skewphos配体的阳离子铑（I）配合物被证明是一种高度对映选择性的催化剂，用于1，6-烯炔与三取代烯烃的不对称碳环化以控制螺环的季铵立体中心。
A cationic rhodium(I) complex having a skewphos ligand is shown to be a highly enantioselective catalyst for asymmetric carbocyclization of 1,6-enynes with tri-substituted olefins to control quaternary stereogenic centers of spiro-rings.