The first samarium(II)-mediated aryl radical cyclisation onto an aromatic ring
The first samarium(II)-mediated aryl radical cyclisation onto an aromatic ring
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DOI：
10.1039/b410457a
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发表时间：
2004-01-01
影响因子：
4.9
通讯作者：
Tanaka, T
中科院分区：
文献类型：
--
作者：
Ohno, H;Iwasaki, H;Tanaka, T
芳基自由基的分子内芳基化介导的SmI 2/HMPA在i-PrOH的存在下，得到螺环和/或减少电影环化的产品，而在i-PrOH的情况下的反应得到rearomatised稠环。
Intramolecular arylation of aryl radicals was mediated by SmI2/HMPA in the presence of i-PrOH to give spirocycles and/or reduced cine-cyclised products, while the reaction in the absence of i-PrOH gave the rearomatised fused rings.