Synthetic approaches on conjugation of poly(2-oxazoline)s with vinyl based polymers
Synthetic approaches on conjugation of poly(2-oxazoline)s with vinyl based polymers
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DOI：
10.1016/j.eurpolymj.2019.07.047
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发表时间：
2019-10-01
影响因子：
6
通讯作者：
Becer, C. Remzi
中科院分区：
文献类型：
--
作者：
Drain, Ben A.;Becer, C. Remzi
2-恶唑啉基聚合物在过去十年中因其在生物医学应用和润滑方面的独特性能而受到越来越多的关注。它们与通常通过受控/“活性”聚合技术合成的广泛使用的聚合物相结合，可以设计新颖的聚合物结构，并进一步扩大聚（2-恶唑啉）基材料的性能范围。然而，要实现这些聚合物的成功组合存在一些合成挑战，文献中报道了各种技术，例如点击反应、大分子单体和异双功能引发剂来克服这些挑战。在这篇综述中，讨论了将聚（2-恶唑啉）与乙烯基聚合物结合的各种合成方法，包括每种方法的优缺点。
2-oxazoline based polymers are attracting more and more attention in the last decade owing to their unique properties not only in biomedical applications but also in lubrication. Their combination with widely used polymers that are usually synthesized via controlled/"living" polymerisation techniques allows the design of novel polymer architectures and further increases the range of properties accessible from poly(2-oxazoline) based materials. However, there are several synthetic challenges to achieve a successful combination of these polymers and various techniques, such as click reactions, macromonomers, and heterobifunctional initiators have been reported in the literature to overcome these challenges. In this review, various synthetic methods to combine poly(2-oxazoline)s with vinyl based polymers have been discussed including the pros and cons of each method.