Novel polycyclic guanidine alkaloids from two marine sponges of the genus Monanchora
Novel polycyclic guanidine alkaloids from two marine sponges of the genus Monanchora
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DOI：
10.1021/np990403g
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发表时间：
2000-02-01
影响因子：
5.1
通讯作者：
Van Soest, RWM
中科院分区：
文献类型：
--
作者：
Braekman, JC;Daloze, D;Van Soest, RWM
在单锚属（Monanchora）海绵中发现了两种新的多环胍类生物碱，其骨架为（5，6，8 b）-三氮杂四氢苊烯。通过详细的光谱分析确定了它们的结构。脱氢巴茨拉定C（1）是从M. arbuscula和crambescidins 359（2）和431（3）。有爪的。这些研究结果的化学分类学的影响进行了讨论。
Two marine sponges of the genus Monanchora (Poecilosclerida, Crambeidae) have been found to contain new polycyclic guanidine alkaloids bearing the (5,6,8b)-triazaperhydroacenaphthylene skeleton. Their structures have been determined by detailed spectroscopic analysis. Dehydrobatzelladine C (1) has been isolated from M. arbuscula and crambescidins 359 (2) and 431 (3) from M. unguiculata. The chemotaxonomic implications of these findings are discussed.