Photocatalytic Overall Water Splitting on RuO2-loaded Sm3+-doped CeO2 with Heterogenous Doping Structure

Photocatalytic Overall Water Splitting on RuO2-loaded Sm3+-doped CeO2 with Heterogenous Doping Structure
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DOI:
10.1246/cl.180876
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发表时间:
2019-03-01
期刊:
影响因子:
1.6
通讯作者:
Saito, Nobuo
Saito, Nobuo
中科院分区:
化学4区
文献类型:
--
作者:
Hou, Honghao;Watanabe, Katsuki;Saito, Nobuo

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研究了负载Sm ~(3+)的CeO_2/RuO_2光催化分解水为氢和氧的性能。纯CeO 2催化剂的活性很低,而固相反应法合成的具有非均相掺杂结构的Sm ~(3+)掺杂CeO 2催化剂的活性很高,而共沉淀法合成的具有均相掺杂结构的Sm ~(3+)掺杂CeO 2催化剂的活性很低。本文研究了光催化活性与表面掺杂结构的关系。
Photocatalytic overall water splitting into hydrogen and oxygen on RuO2-loaded Sm3+-doped CeO2 was examined. Pure CeO2 showed a negligible small activity, however Sm3+ doped CeO2 with heterogeneous doping structure synthesized by solid state reaction exhibited an efficient activity, whereas Sm3+-doped CeO2 with homogeneous doping structure showed little activity when prepared by co-precipitation method. In this study, the relation between photocatalytic activity and surface doping structure was investigated.