Breakdown of a stationary solution to the Nernst–Planck–Poisson equations

Breakdown of a stationary solution to the Nernst–Planck–Poisson equations
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Nernst–Planck–Poisson 方程平稳解的分解

DOI:
10.1039/f29797500936
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发表时间:
1979
期刊:
Journal of the Chemical Society, Faraday Transactions
影响因子:
--
通讯作者:
L. Segel
L. Segel
中科院分区:
--
文献类型:
--
作者:
I. Rubinstein;L. Segel

文献摘要

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该报告显示了在足够高的电压下,描述电流通过与理想阳离子交换膜相邻的未搅拌电解质层的方程的代表性稳定解的振荡不稳定性。这种不稳定性可能是进一步“类湍流”转变的预兆,与在高电压下观察到的不稳定相对应。
This report shows an oscillatory instability, at sufficiently high voltage, of a representative steady solution to equations describing the passage of current through an unstirred layer of electrolyte adjacent to an ideal cation exchange membrane. This instability may be the harbinger of further “turbulent-like” transitions that correspond to observed unsteadiness at high voltages.