Vanadium-catalysed regioselective hydroboration of epoxides for synthesis of secondary alcohols
Vanadium-catalysed regioselective hydroboration of epoxides for synthesis of secondary alcohols
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DOI：
10.1039/d3dt01865b
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发表时间：
2023-08-08
影响因子：
4
通讯作者：
Neary，Michelle C.
中科院分区：
文献类型：
--
作者：
Zhang，Guoqi;Zeng，Haisu;Neary，Michelle C.
报道了一种由氧化还原活性三联吡啶配体负载的二烷基钒配合物催化的硼氢化反应的区域选择性环氧开环反应。仲醇通过有效的Markovnikov硼氢化末端环氧化物，以高收率获得，展示了地球丰富的钒（III）配合物的新的催化应用。
Regioselective epoxide ring-opening through hydroboration catalysed by a vanadium(III) dialkyl complex supported by a redox-active terpyridine ligand is reported. Secondary alcohols were obtained in high yields via effective Markovnikov hydroboration of terminal epoxides, showcasing a new catalytic application of an earth-abundant vanadium(III) complex.