Fabrication and Fuel-Cell Properties of Sm-Doped CeO2 Electrolyte Film by Electrophoretic Deposition

Fabrication and Fuel-Cell Properties of Sm-Doped CeO2 Electrolyte Film by Electrophoretic Deposition
复制标题

电泳沉积钐掺杂 CeO2 电解质薄膜的制备及其燃料电池性能

DOI:
10.4028/www.scientific.net/kem.350.175
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发表时间:
2007
期刊:
Key Engineering Materials
影响因子:
--
通讯作者:
M. Miyayama
M. Miyayama
中科院分区:
--
文献类型:
--
作者:
S. Nakayama;M. Miyayama

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采用电泳沉积法(EPD)在NiO-SDC阳极衬底上制备了Ce0.8Sm0.2O1.9 (SDC)电解质膜,用于中温固体氧化物燃料电池(sofc)。通过与衬底共烧,制备了致密无裂纹的薄膜。采用La0.6Sr0.4CoO3-δ阴极的SDC电解质膜的电池在600℃下的功率密度为281 mW/cm2,电解质电阻为0.064 cm2。EPD在SDC上形成薄膜,可以有效地降低电解质电阻。
Electrolyte films of Ce0.8Sm0.2O1.9 (SDC) were prepared on NiO-SDC anode substrates by electrophoretic deposition (EPD) for intermediate-temperature solid oxide fuel cells (SOFCs). Dense and crack-free films were fabricated by cofiring the films and substrates. A cell using an SDC electrolyte film with a La0.6Sr0.4CoO3-δ cathode exhibited a power density of 281 mW/cm2 and an electrolyte resistance of 0.064 cm2 at 600°C. The film formation of SDC by EPD was found effective in decreasing the electrolyte resistance.