Recent contributions to the aqueous coordination chemistry of beryllium
Recent contributions to the aqueous coordination chemistry of beryllium
复制标题
对铍水配位化学的最新贡献
DOI：
10.1016/s0010-8545(00)00406-9
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发表时间：
2001
影响因子：
20.6
通讯作者：
H. Schmidbaur
中科院分区：
文献类型：
--
作者：
H. Schmidbaur
本文综述了铍的水溶液配位化学和结构化学，重点介绍了简单的氟化物、水合、羟基、氧代和过氧配合物。络合物的形成与较重的卤化物和chalkogenide阴离子在水溶液中不起作用。铍的形成和结构的羧酸盐，氧代羧酸盐，二羧酸盐，羟基羧酸盐，碳酸盐，酚盐，烯醇盐，和多元醇盐在不同的pH值制度下也被认为是在铍的生物无机化学的背景下。铍与氨基酸的配位化学几乎完全未被探索。
The aqueous coordination chemistry and the structural chemistry of beryllium are reviewed focusing on simple fluoride, aquo, hydroxo, oxo, and peroxo complexes. Complex formation with the heavier halide and chalkogenide anions plays no role in aqueous solution. Formation and structure of beryllium carboxylates, oxo carboxylates, dicarboxylates, hydroxy-carboxylates, carbonates, phenolates, enolates, and polyolates under various pH regimes are also considered in the context of the bioinorganic chemistry of beryllium. The coordination chemistry of beryllium with amino acids is almost completely unexplored.