Efficient and clean photoreduction of CO(2) to CO by enzyme-modified TiO(2) nanoparticles using visible light.
Efficient and clean photoreduction of CO(2) to CO by enzyme-modified TiO(2) nanoparticles using visible light.
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DOI:
10.1021/ja910091z
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发表时间:
2010-02-24
影响因子:
15
通讯作者:
Armstrong, Fraser A.
中科院分区:
文献类型:
--
作者:
Woolerton, Thomas W.;Sheard, Sally;Reisner, Erwin;Pierce, Elizabeth;Ragsdale, Stephen W.;Armstrong, Fraser A.
A hybrid enzyme-nanoparticle system is described for achieving clean reduction of CO2 to CO using visible light as the energy source. An aqueous dispersion of TiO2 nanoparticles modified by attachment of carbon monoxide dehydrogenase (CODH) and a Ru photosensitizer produces CO at a rate of 250 μmol CO (g TiO2)-1 h-1 when illuminated with visible light at pH 6 and 20 °C.
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