Efficient and clean photoreduction of CO(2) to CO by enzyme-modified TiO(2) nanoparticles using visible light.

Efficient and clean photoreduction of CO(2) to CO by enzyme-modified TiO(2) nanoparticles using visible light.
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DOI:
10.1021/ja910091z
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发表时间:
2010-02-24
影响因子:
15
通讯作者:
Armstrong, Fraser A.
Armstrong, Fraser A.
中科院分区:
化学1区
文献类型:
--
作者:
Woolerton, Thomas W.;Sheard, Sally;Reisner, Erwin;Pierce, Elizabeth;Ragsdale, Stephen W.;Armstrong, Fraser A.

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描述了一种混合酶-纳米颗粒系统,用于使用可见光作为能源实现CO2到CO的清洁还原。通过一氧化碳脱氢酶(CODH)和Ru光敏剂的附着改性的TiO 2纳米颗粒的水性分散体在pH 6和20 °C下用可见光照射时以250 μmol CO(g TiO 2)-1 h-1的速率产生CO。
A hybrid enzyme-nanoparticle system is described for achieving clean reduction of CO2 to CO using visible light as the energy source. An aqueous dispersion of TiO2 nanoparticles modified by attachment of carbon monoxide dehydrogenase (CODH) and a Ru photosensitizer produces CO at a rate of 250 μmol CO (g TiO2)-1 h-1 when illuminated with visible light at pH 6 and 20 °C.
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