The Reaction of Organozinc Compounds with an Aldehyde within a Crystalline Molecular Flask
The Reaction of Organozinc Compounds with an Aldehyde within a Crystalline Molecular Flask
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DOI：
10.1002/anie.201002053
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发表时间：
2010-01-01
影响因子：
16.6
通讯作者：
Fujita, Makoto
中科院分区：
文献类型：
--
作者：
Ikemoto, Koki;Inokuma, Yasuhide;Fujita, Makoto
有机锌加成反应是在多孔配位网络（见图）中以单晶到单晶的方式在醛上进行的，产物结构通过X射线衍射明确确定。此外，在单晶中的一锅两步反应提供了来自醛的酯，而没有网络损失结晶度。© 2010 Wiley-VCH Verlag GmbH & Co. KGaA，魏因海姆。
(Figure Presented) Organozinc addition reactions were carried out on an aldehyde within a porous coordination network (see picture) in a single-crystal-to-single-crystal fashion, and the product structure was unambiguously determined by X-ray diffraction. Moreover, a one-pot two-step reaction in a single crystal furnished an ester from an aldehyde without the network losing crystallinity.© 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.