Advances in Molten Salt Synthesis of Non‐oxide Materials

Advances in Molten Salt Synthesis of Non‐oxide Materials
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DOI:
10.1002/eem2.12339
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发表时间:
2021-12
影响因子:
15
通讯作者:
Shaolong Li;Jianxun Song;Yusi Che;S. Jiao;Ji-lin He;Bin Yang
Shaolong Li;Jianxun Song;Yusi Che;S. Jiao;Ji-lin He;Bin Yang
中科院分区:
材料科学1区
文献类型:
--
作者:
Shaolong Li;Jianxun Song;Yusi Che;S. Jiao;Ji-lin He;Bin Yang

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非氧化物材料的性能不断被揭示,其在陶瓷、能源、催化等领域的应用日益广泛。无论是传统的二元材料还是MAX相,环保、高效、经济、易于放大的制备方法一直是人们关注的焦点。熔盐合成在获得非氧化物材料方面表现出无与伦比的优势。此外,随着熔盐合成工艺的发展,其规模化生产也显示出巨大的潜力。本文综述了熔盐合成在制备二元非氧化物相和MAX相方面的最新进展,以及一些新颖的工艺。详细讨论了某些材料的反应机理和合成条件的影响。论文最后讨论了熔盐合成在非氧化物材料中的应用前景和未来研究趋势。
The properties of non‐oxide materials are continuously revealed, and their applications in the fields of ceramics, energy, and catalysis are increasingly extensive. Regardless of the traditional binary materials or the MAX phases, the preparation methods, which are environmentally friendly, efficient, economical, and easy to scale‐up, have always been the focus of attention. Molten salt synthesis has demonstrated unparalleled advantages in achieving non‐oxide materials. In addition, with the development of the process in molten salt synthesis, it also shows great potential in scale‐up production. In this review, the recent progress of molten salt synthesis in the preparation of binary non‐oxide and MAX phase is reviewed, as well as some novel processes. The reaction mechanisms and the influence of synthetic conditions for certain materials are discussed in detail. The paper is finalized with the discussion of the application prospect and future research trends of molten salt synthesis in non‐oxide materials.