Acceptorless Photocatalytic Dehydrogenation for Alcohol Decarbonylation and Imine Synthesis
Acceptorless Photocatalytic Dehydrogenation for Alcohol Decarbonylation and Imine Synthesis
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DOI：
10.1002/anie.201203556
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发表时间：
2012-01-01
影响因子：
16.6
通讯作者：
Sadow, Aaron D.
中科院分区：
文献类型：
--
作者：
Ho, Hung-An;Manna, Kuntal;Sadow, Aaron D.
它已经曝光：对高含氧材料转化的新兴趣激发了对伯醇到烷烃、CO和H（2）的有机金属催化的光催化分解脱羰的研究。甲醇、乙醇、苯甲醇和环己烷甲醇容易脱羰基。光催化剂对胺脱氢反应也有催化活性，生成N-烷基醛亚胺和H（2）。
It has come to light: Renewed interest in conversions of highly oxygenated materials has motivated studies of the organometallic-catalyzed photocatalytic dehydrogenative decarbonylation of primary alcohols into alkanes, CO, and H (2). Methanol, ethanol, benzyl alcohol, and cyclohexanemethanol are readily decarbonylated. The photocatalysts are also active for amine dehydrogenation to give N-alkyl aldimines and H (2).