Chiral N,N’‐Dioxide/Tm(OTf)3 Complex‐Catalyzed Asymmetric Bisvinylogous Mannich Reaction of Silyl Ketene Acetal with Aldimines
Chiral N,N’‐Dioxide/Tm(OTf)3 Complex‐Catalyzed Asymmetric Bisvinylogous Mannich Reaction of Silyl Ketene Acetal with Aldimines
复制标题
手性N,N-二氧化物/Tm(OTf)3配合物-催化硅烯酮缩醛与醛亚胺的不对称双乙烯基曼尼希反应
DOI：
10.1002/adsc.201900164
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发表时间：
2019
影响因子：
5.4
通讯作者：
Xiaoming Feng
中科院分区：
文献类型：
--
作者：
Sijia Zou;Weiwei Li;Kai Fu;Weidi Cao;Lili Lin;Xiaoming Feng
An enantioselective bisvinylogous Mannich reaction of silyl ketene acetal with aldimines has been realized by using a chiralN,N′‐dioxide/Tm(OTf)3complex as catalyst, providing an effective method to synthesize chiralζ‐amino‐α,β,γ,δ‐unsaturated carbonyl compounds.
