Scaling of Suprastructure and Dynamics in Pure and Mixed Debye Liquids

Scaling of Suprastructure and Dynamics in Pure and Mixed Debye Liquids
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纯德拜液体和混合德拜液体中上层结构和动力学的标度

DOI:
10.1007/978-3-319-72706-6_5
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发表时间:
2018
期刊:
影响因子:
--
通讯作者:
R. Böhmer
R. Böhmer
中科院分区:
--
文献类型:
--
作者:
S. P. Bierwirth;J. Bolle;S. Bauer;C. Sternemann;C. Gainaru;M. Tolan;R. Böhmer

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德拜或近德拜类型的超分子弛豫的特征是一元醇、水和几种其他液体。主要集中在宽带介电谱,剪切流变学,X射线衍射和近红外吸收的结果,成链和成环的一元醇的标度性能进行了研究。偏离理想的混合行为,在二元溶液中,涉及这些液体在其过冷状态给予特别关注。目前的调查是选择性的,而不是全面的,重点是在这一科学领域令人兴奋的最新发展。虽然本章中总结的大部分研究都是基于线性响应和环境压力条件下进行的实验和分析,但也简要地涉及了超出这些范围的现象。最后,针对在微观水平上发生在这些液体中的分子动力学的忠实代表性,从实验技术的互补应用以及未来发展的前景所产生的总体方面进行了讨论。
Supramolecular relaxations of the Debye or near-Debye type are featured by monohydroxy alcohols, water, and several other liquids. Mainly focusing on results from broadband dielectric spectroscopy, shear rheology, X-ray diffraction, and near-infrared absorption, scaling properties of chain-forming and ring-forming monohydroxy alcohols are examined. Deviations from ideal-mixing behavior in binary solutions involving these liquids in their supercooled state are given particular attention. The present survey is selective rather than comprehensive with a focus on exciting recent developments in this scientific area. Although most of the research summarized in this chapter is based on experiments and analyses carried out under linear-response and ambient-pressure conditions, phenomena emerging beyond these regimes are briefly touched upon as well. Finally, aiming at a faithful representation of the molecular dynamics taking place in these liquids at the microscopic level, overarching aspects arising from the complementary application of experimental techniques as well as perspectives for future developments are discussed.
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