Effect of thermally grown oxides on colour development of stainless steel
Effect of thermally grown oxides on colour development of stainless steel
复制标题
热生长氧化物对不锈钢显色的影响
DOI：
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发表时间：
2015
期刊：
影响因子：
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通讯作者：
G. Wilcox
中科院分区：
文献类型：
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作者：
R. Higginson;C. P. Jackson;E. L. Murrell;P. A. Z. Exworthy;R. Mortimer;D. Worrall;G. Wilcox
摘要不锈钢用于一系列应用中，它们的颜色呈现能力具有美学价值。虽然热着色（热着色）是已知的，特别是就其对焊缝的影响而言，但尚未详细考虑热着色不锈钢的表面显影。本文演示了光亮退火304不锈钢在温度下随时间的颜色发展。颜色的发展已被量化，使用彩色分光光度法和相关的表面氧化物特征的生长通过扫描电子显微镜和X射线光电子能谱（XPS）的化学配置文件的颜色。随着时间的推移，氧化物厚度和化学性质都有明显的发展，随着时间的推移，在样品表面上看到的主要特征是小结节。氧化物已被证明包括外部富铁氧化物和内部铬/铁尖晶石层。
Abstract Stainless steels are used in an array of applications where their ability to take on colour is of aesthetic value. Although thermal colouring (heat tinting) is known, particularly in terms of its effect on welds, the surface development of thermally coloured stainless steel has not been considered in detail. This paper demonstrates the colour development of a bright annealed 304 stainless steel with time at temperature. The colour development has been quantified using colour spectrophotoscopy and the colour related to the growth of surface oxide features by scanning electron microscopy and the chemical profiles by X-ray photoelectron spectroscopy (XPS). There is a clear development of both the oxide thickness and chemistry, with increasing time with small nodules being the main features seen across the surface of the samples with time. The oxides have been shown to comprise of an outer iron rich oxide and an inner chromium/iron spinel layer.