Standard electrode potentials involving radicals in aqueous solution: inorganic radicals (IUPAC Technical Report)
Standard electrode potentials involving radicals in aqueous solution: inorganic radicals (IUPAC Technical Report)
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DOI：
10.1515/pac-2014-0502
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发表时间：
2015-12-01
影响因子：
1.8
通讯作者：
Wardman, Peter
中科院分区：
文献类型：
--
作者：
Armstrong, David A.;Huie, Robert E.;Wardman, Peter
推荐了25 ℃水溶液中选择无机自由基的标准电位。这些建议基于批判性和彻底的文献综述，并从各种文献报告中进行推导。推荐的数据汇总在标准电位、生成吉布斯能、自由基pK（a）和半聚合平衡常数表中。在所有情况下，都提供了目前对不确定性的最佳估计。随附了一组广泛的数据表，提供原始文献参考，总结实验结果，并描述导致每个建议的决策和程序。
Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 degrees C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical pK(a)'s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations.