Synthesis and chiral recognition of an optically active bis-crown ether incorporating a diphenanthrylnaphthalene moiety as the chiral centre
Synthesis and chiral recognition of an optically active bis-crown ether incorporating a diphenanthrylnaphthalene moiety as the chiral centre
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以二菲基萘为手性中心的光学活性双冠醚的合成及手性识别
DOI：
10.1039/c39870000168
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发表时间：
1987
期刊：
影响因子：
--
通讯作者：
H. Chikamatsu
中科院分区：
文献类型：
--
作者：
Koji Yamamoto;H. Yumioka;Y. Okamoto;H. Chikamatsu
合成了一种新型的具有光学活性的双冠醚(-)-(S，S)-(7)，其手性中心为二苯基萘，考察了其手性识别性能，结果表明，(-)-(S，S)-(7)对1，6-二苯基六亚甲基-1，6-二胺具有较高的对映体选择性。
A novel optically active double-layered bis-crown ether (–)-(S,S)-(7) with a diphenanthrylnaphthalene moiety as the chiral centre has been prepared, and examination of its chiral recognition behaviour showed that (–)-(S,S)-(7) has a high enantiomer selectivity for 1,6-diphenylhexamethylene-1,6-diamine.